Nikkei Electronics Asia -- February 2007
Tech Feature
Blue First: High-Output LEDs on Si Substrate

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Jan 26, 2007 16:09 Nikkei Electronics Asia
Technology start-up Shimei Semiconductor Co Ltd of Japan has developed a GaN light emitting diode (LED) with high optical output - but on a Si substrate. The optical output of the blue LED is 10mW max at 20mA, which is on a par with the most-commonly used LEDs on sapphire substrates.
In general, LEDs can be manufactured on Si substrates for lower cost, for reasons including (1) large-diameter Si wafers are suited to volume production, (2) they are cheaper than sapphire substrates, and (3) they are more flexible and easier to work than sapphire. In spite of these advantages, sapphire substrates are widely used because Si substrates are more susceptible to crystal lattice defects, which can degrade optical output.
To resolve this problem, Shimei Semiconductor replaced some of the GaN with AlInGaN, preventing lattice defects from occurring. The developed LED has an emission wavelength of 450nm, and uses AlInGaN in the emission layer. The chip measures 0.3mm square. The firm also makes green LEDs on Si substrates.
The blue LEDs are scheduled to sample-ship in April 2007, and the firm is ramping up for 3-million units/month production. In addition to bare chips it is also considering providing them on wafers. They currently use 2-inch Si wafers.

AlInGaN Buffer Layers
When a GaN film is grown on a Si substrate, the GaN film is susceptible to cracks, displacement and other defects because of the large differences in characteristics, including coefficient of thermal expansion and lattice constant. Shimei Semiconductor placed an AlInGaN buffer layer between the Si substrate and the n-type GaN layer to ameliorate this (Fig a). There are several dozen layers of AlInGaN with varying compositions.
The higher output involved not only reducing lattice defects, but also minimizing the absorption of output from the emission layer by the Si substrate. The multi-layer AlInGaN buffer contains a distributed Bragg reflector (DBR), which boosts optical output by about 1.5 times.
The DBR consists of alternating layers of two materials with different refractive indices, reflecting specific wavelengths. The composition of the AlInGaN was varied to create layers with different refractive indices. It would also have been possible to use a metal mirror DBR, but the firm chose this approach because it could all be formed on a film growth system.
Another measure to minimize lattice defects was optimization of growth parameters such as temperature and pressure in the metal organic chemical vapor deposition (MOCVD) process used to fabricate the LEDs. The LED chip film (excluding the substrate) is 4 to 5um in thickness, relatively thick, for the same reason. The n-type electrode was mounted at the base of the LED chip, making it a vertical structure with electrodes top and bottom. LEDs mounted on sapphire substrates grind down
the top LED layer for the n-type electrode because sapphire is an insulator. With Si, however, no grinding process is needed, contributing to lower cost.
The company also hopes to create a white LED of AlInGaN by about 2010. Engineers hope to create red (R), green (G) and blue (B) emission layers of AlInGaN on a single chip, as well as using the material for the n- and p-type layers (Fig b). By using AlInGaN for the n- and p-type layers, the firm believes emission efficiency will be higher than that of GaN.

by Tadashi Nezu

NIKKEI ERECTRONICS ASIA

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